Tuesday, October 23, 2012

Nuclei

Ans: 1
(a) Mass of lithium isotope ,m1= 6.01512 u
Mass of lithium isotope ,m2= 7.01600 u
Abundance of ,η1= 7.5%
Abundance of ,η2= 92.5%
The atomic mass of lithium atom is given as:

(b) Mass of boron isotope ,m1= 10.01294 u
Mass of boron isotope ,m2= 11.00931 u
Abundance of ,η1= x%
Abundance of ,η2= (100 − x)%
Atomic mass of boron, m= 10.811 u
Theatomic mass of boron atom is given as:

And100 − x= 80.11%
Hence,the abundance of is 19.89% and that of is 80.11%.
Ans: 2
Atomic mass of ,m1= 19.99 u
Abundanceof ,η1= 90.51%
Atomic mass of ,m2 = 20.99 u
Abundance of ,η2= 0.27%
Atomic mass of ,m3 = 21.99 u
Abundance of ,η3= 9.22%
Theaverage atomic mass of neon is given as:


Ans: 3
Atomic mass of nitrogen,m = 14.00307 u
Anucleus of nitrogen contains 7 protons and 7 neutrons.
Hence,the mass defect of this nucleus, Δm= 7mH+ 7mnm
Where,
Mass of a proton, mH= 1.007825 u
Mass of a neutron, mn= 1.008665 u
∴Δm= 7 × 1.007825 + 7 × 1.008665 − 14.00307
= 7.054775 + 7.06055 − 14.00307
= 0.11236 u
But1 u = 931.5 MeV/c2
Δm= 0.11236 × 931.5 MeV/c2
Hence,the binding energy of the nucleus is given as:
Eb= Δmc2
Where,
c= Speed of light
Eb= 0.11236 ×931.5
= 104.66334 MeV
Hence, the binding energy of a nitrogen nucleus is 104.66334 MeV.

Ans: 4
Atomicmass of,m1= 55.934939 u
nucleus has 26 protons and (56 − 26) = 30 neutrons
Hence,the mass defect of the nucleus, Δm= 26 × mH+ 30 × mnm1
Where,
Mass of a proton, mH= 1.007825 u
Mass of a neutron, mn= 1.008665 u
∴Δm= 26 × 1.007825 + 30 × 1.008665 − 55.934939
= 26.20345 + 30.25995 − 55.934939
= 0.528461 u
But 1 u = 931.5 MeV/c2
∴Δm= 0.528461 × 931.5 MeV/c2
The binding energy of this nucleus is given as:
Eb1= Δmc2
Where,
c= Speed of light
Eb1= 0.528461 × 931.5
= 492.26 MeV
Average binding energy per nucleon
Atomic mass of,m2= 208.980388 u
nucleus has 83 protons and (209 − 83) 126 neutrons.
Hence,the mass defect of this nucleus is given as:
Δm' = 83 × mH+ 126 × mnm2
Where,
Mass of a proton, mH= 1.007825 u
Mass of a neutron, mn= 1.008665 u
∴Δm' = 83 × 1.007825 + 126 × 1.008665 − 208.980388
= 83.649475 + 127.091790 − 208.980388
= 1.760877 u
But 1 u = 931.5 MeV/c2
∴Δm' = 1.760877 × 931.5 MeV/c2
Hence, the binding energy of this nucleus is given as:
Eb2= Δm'c2
= 1.760877 × 931.5
= 1640.26 MeV
Average bindingenergy per nucleon =

Ans: 5
Mass of a copper coin, m’= 3 g
Atomic mass ofatom, m = 62.92960 u
The total number of atoms in the coin
Where,
NA= Avogadro’s number = 6.023 × 1023atoms /g
Mass number = 63 g

nucleus has 29 protons and (63 − 29) 34 neutrons
Mass defect of this nucleus, Δm' = 29 × mH+ 34 × mnm
Where,
Mass of a proton, mH= 1.007825 u
Mass of a neutron, mn= 1.008665 u
∴Δm' = 29 × 1.007825 + 34 × 1.008665 − 62.9296
= 0.591935 u
Mass defect of all the atoms present in the coin, Δm= 0.591935 × 2.868 × 1022
= 1.69766958 × 1022u
But 1 u = 931.5 MeV/c2
∴Δm= 1.69766958 × 1022× 931.5 MeV/c2
Hence, the binding energy of the nuclei of the coin is given as:
Eb=Δmc2
= 1.69766958 × 1022× 931.5
= 1.581 × 1025MeV
But 1 MeV = 1.6 × 10−13J
Eb= 1.581 × 1025× 1.6 × 10−13
= 2.5296 × 1012J
Thismuch energy is required to separate all the neutrons and protons from the given coin.

Ans: 6
α is a nucleus of helium and βis an electron (efor βand e+for β+).In every α-decay, there is a loss of 2 protons and 4 neutrons. In every β+-decay, there is a loss of 1 proton and a neutrino is emitted from the nucleus. In every β-decay, there is a gain of 1 proton and an antineutrino is emitted from the nucleus.
For the given cases, the various nuclear reactions can be written as:


Ans: 7
Half-life of the radioactive isotope = Tyears
Original amount of the radioactive isotope = N0
(a) After decay, the amount of the radioactive isotope = N
It is given that only 3.125% of N0remains after decay. Hence, we can write:

Where,
λ= Decay constant
t= Time

Hence, the isotope will take about 5Tyears to reduce to 3.125% of its original value.
(b) After decay, the amount of the radioactive isotope = N
It is given that only 1% of N0remains after decay. Hence, we can write:

Since,λ= 0.693/T

Hence, the isotope will take about 6.645Tyears to reduce to 1% of its original value.

Ans: 8
Decay rate of living carbon-containing matter, R= 15 decay/min
Let N be the number of radioactive atoms present in a normal carbon-containing matter.
Half life of,= 5730 years
The decay rate of the specimen obtained from the Mohenjodaro site:
R' = 9 decays/min
Let N' be the number of radioactive atoms present in the specimen during the Mohenjodaro period.
Therefore, we can relate the decay constant, λand time, tas:

Hence, the approximate age of the Indus-Valley civilisation is 4223.5 years.

Ans: 9
The strength of the radioactive source is given as:

Where,
N= Required number of atoms
Half-life of,= 5.3 years
= 5.3 × 365 × 24 × 60 × 60
= 1.67 × 108s
For decay constant λ,we have the rate of decay as:

Where,λ


For:
Mass of 6.023 × 1023 (Avogadro’s number) atoms = 60 g
Mass of atoms
Hence,the amount of necessary for the purpose is 7.106 × 10−6g.

Ans: 10
Half life of,= 28 years
= 28 × 365 × 24 × 60 × 60
= 8.83 × 108s
Mass of the isotope, m= 15 mg
90 g of atom contains 6.023 × 1023(Avogadro’s number) atoms.
Therefore,15 mg of contains:

Rate of disintegration,
Where,
λ =Decay constant

Hence, the disintegration rate of 15 mg of the given isotope is
7.878 × 10
10atoms/s.

Ans: 11
Nuclear radius of the gold isotope= RAu
Nuclearradius of the silver isotope= RAg
Mass number of gold, AAu= 197
Mass number of silver, AAg= 107
The ratio of the radii of the two nuclei is related with their mass numbers as:

Hence, the ratio of the nuclear radii of the gold and silver isotopes is about 1.23.

Ans: 12
(a) Alpha particle decay of emits a helium nucleus. As a result, its mass number reduces to (226 −4) 222 and its atomic number reduces to (88 − 2) 86. This is shown in the following nuclear reaction.

Q-value of
emittedα-particle = (Sum of initial mass − Sum of final mass) c2
Where,
c= Speed of light
It is given that:

Q-value = [226.02540 − (222.01750 + 4.002603)] u c2
= 0.005297 u
c2
But1 u = 931.5 MeV/c2
Q= 0.005297 × 931.5 4.94 MeV
Kinetic energy of the α-particle

(b) Alpha particle decay of is shown by the following nuclear reaction.

It is given that:
Mass of = 220.01137 u
Mass of = 216.00189 u
Q-value =
641 MeV
Kinetic energy of the α-particle
= 6.29 MeV

Ans: 13
The given nuclear reaction is:

Atomic mass of = 11.011434 u
Atomic mass of
Maximum energy possessed by the emitted positron = 0.960 MeV
The change in the Q-value (ΔQ) of the nuclear masses of the nucleus is given as:

Where,
me= Mass of an electron or positron = 0.000548 u
c= Speed of light
m’= Respective nuclear masses
If atomic masses are used instead of nuclear masses, then we have to add 6 mein the case ofand 5 mein the case of.
Hence, equation (1) reduces to:

∴ΔQ= [11.011434 − 11.009305 − 2 ×0.000548] c2
= (0.001033 c2) u
But 1 u = 931.5 Mev/c2
∴ΔQ= 0.001033 ×931.5 0.962 MeV
The value of Qis almost comparable to the maximum energy of the emitted positron.

Ans: 14
In emission, the number of protons increases by 1, and one electron and an antineutrino are emitted from the parent nucleus.
emission of the nucleus is given as:

It is given that:
Atomic mass of = 22.994466 u
Atomic mass of = 22.989770 u
Mass of an electron, me= 0.000548 u
Q-value of the given reaction is given as:

There are 10 electrons in and 11 electrons in. Hence, the mass of the electron is cancelled in the Q-value equation.

The daughter nucleus is too heavy as compared to and. Hence, it carries negligible energy. The kinetic energy of the antineutrino is nearly zero. Hence, the maximum kinetic energy of the emitted electrons is almost equal to the Q-value, i.e., 4.374 MeV.

Ans: 15
(i) The given nuclear reaction is:

It is given that:
Atomic mass
Atomic mass
Atomic mass
According to the question, the Q-value of the reaction can be written as:

The negativeQ-value of the reaction shows that the reaction is endothermic.
(ii) The given nuclear reaction is:

It is given that:
Atomic mass of
Atomic mass of
Atomic mass of
TheQ-value of this reaction is given as:

The positive Q-value of the reaction shows that the reaction is exothermic.

Ans: 16
The fission of can be given as:

It is given that:
Atomic mass of = 55.93494 u
Atomic mass of
TheQ-value of this nuclear reaction is given as:

TheQ-value of the fission is negative. Therefore, the fission is not possible energetically. For an energetically-possible fission reaction, theQ-value must be positive.

Ans: 17
Average energy released per fission of,
Amount of pure,m = 1 kg = 1000 g
NA= Avogadro number = 6.023 ×1023
Mass number of= 239 g
1 mole of contains NAatoms.
mg of contains

Total energy released during the fission of 1 kg ofis calculated as:

Hence,is released if all the atoms in 1 kg of pure undergo fission.

Ans: 18
Half life of the fuel of the fission reactor,years
= 5 × 365 × 24 × 60 × 60 s
We know that in the fission of 1 g of nucleus, the energy released is equal to 200 MeV.
1 mole, i.e., 235 g of contains 6.023 ×1023atoms.
1 g contains
The total energy generated per gram ofis calculated as:

The reactor operates only 80% of the time.
Hence, the amount of consumed in 5 years by the 1000 MW fission reactor is calculated as:

Initial amount of = 2 ×1538 = 3076 kg

Ans: 19
The given fusion reaction is:

Amount of deuterium, m= 2 kg
1 mole, i.e., 2 g of deuterium contains 6.023 ×1023atoms.
2.0 kg of deuterium contains
It can be inferred from the given reaction that when two atoms of deuterium fuse, 3.27 MeV energy is released.
Total energy per nucleus released in the fusion reaction:

Power of the electric lamp, P= 100 W = 100 J/s
Hence, the energy consumed by the lamp per second = 100 J
The total time for which the electric lamp will glow is calculated as:


Ans: 20
When two deuterons collide head-on, the distance between their centres,d is given as:
Radius of 1stdeuteron + Radius of 2nddeuteron
Radius of a deuteron nucleus = 2 fm = 2 ×10−15m
d= 2 ×10−15+ 2 ×10−15 = 4 ×10−15m
Charge on a deuteron nucleus = Charge on an electron = e= 1.6 ×10−19C
Potential energy of the two-deuteron system:

Where,
= Permittivity of free space

Hence, the height of the potential barrier of the two-deuteron system is
360 keV.

Ans: 21
We have the expression for nuclear radius as:
R= R0A1/3
Where,
R0= Constant.
A= Mass number of the nucleus
Nuclear matter density,
Letm be the average mass of the nucleus.
Hence, mass of the nucleus = mA

Hence, the nuclear matter density is independent of A. It is nearly constant.

Ans: 22
Let the amount of energy released during the electron capture process beQ1. The nuclear reaction can be written as:

Let the amount of energy released during the positron capture process beQ2. The nuclear reaction can be written as:

= Nuclear mass of
= Nuclear mass of
= Atomic mass of
= Atomic mass of
me= Mass of an electron
c= Speed of light
Q-value of the electron capture reaction is given as:

Q-value of the positron capture reaction is given as:

It can be inferred that if Q2> 0, then Q1> 0; Also, if Q1> 0, it does not necessarily mean that Q2> 0.
In other words, this means that ifemission is energetically allowed, then the electron capture process is necessarily allowed, but not vice-versa. This is because the Q-value must be positive for an energetically-allowed nuclear reaction.

Ans: 23
Average atomic mass of magnesium, m= 24.312 u
Mass of magnesium isotope,m1= 23.98504 u
Mass of magnesium isotope,m2= 24.98584 u
Mass of magnesium isotope,m3= 25.98259 u
Abundance of,η1= 78.99%
Abundance of,η2= x%
Hence, abundance of,η3= 100 − x− 78.99% = (21.01 − x)%
We have the relation for the average atomic mass as:

Hence, the abundance of is 9.3% and that of is 11.71%.

Ans: 24
For
For
A neutron is removed from anucleus. The corresponding nuclear reaction can be written as:

It is given that:
Mass= 39.962591 u
Mass) = 40.962278 u
Mass= 1.008665 u
The mass defect of this reaction is given as:
Δm=


∴Δm= 0.008978 × 931.5 MeV/c2
Hence, the energy required for neutron removal is calculated as:

For, the neutron removal reaction can be written as:

It is given that:
Mass= 26.981541 u
Mass= 25.986895 u
The mass defect of this reaction is given as:

Hence, the energy required for neutron removal is calculated as:


Ans: 25
Half life of,T1/2 = 14.3 days
Half life of,T’1/2= 25.3 days
nucleus decay is 10% of the total amount of decay.
The source has initially 10% of nucleus and 90% of nucleus.
Suppose after tdays, the source has 10% of nucleus and 90% of nucleus.
Initially:
Number of nucleus = N
Number of nucleus = 9 N
Finally:
Number of
Number of
Fornucleus, we can write the number ratio as:

For, we can write the number ratio as:

On dividing equation (1) by equation (2), we get:

Hence, it will take about 208.5 days for 90% decay of .

Ans: 26
Take a emission nuclear reaction:

We know that:
Mass of m1= 223.01850 u
Mass of m2= 208.98107 u
Mass of,m3= 14.00324 u
Hence, the Q-value of the reaction is given as:
Q= (m1m2m3)c2
= (223.01850 − 208.98107 − 14.00324) c2
= (0.03419 c2) u
But 1 u = 931.5 MeV/c2
Q= 0.03419 × 931.5
= 31.848 MeV
Hence, the Q-value of the nuclear reaction is 31.848 MeV. Since the value is positive, the reaction is energetically allowed.
Now take a emission nuclear reaction:

We know that:
Mass of m1= 223.01850
Mass of m2= 219.00948
Mass of,m3= 4.00260
Q-value of this nuclear reaction is given as:
Q= (m1m2m3)c2
= (223.01850 − 219.00948 − 4.00260) C2
= (0.00642 c2) u
= 0.00642 × 931.5 = 5.98 MeV
Hence, the Qvalue of the second nuclear reaction is 5.98 MeV. Since the value is positive, the reaction is energetically allowed.

Ans: 27
In the fission of, 10 βparticles decay from the parent nucleus. The nuclear reaction can be written as:

It is given that:
Mass of a nucleusm1= 238.05079 u
Mass of a nucleus m2= 139.90543 u
Mass of a nucleus,m3 = 98.90594 u
Mass of a neutronm4= 1.008665 u
Q-value of the above equation,

Where,
m’ = Represents the corresponding atomic masses of the nuclei
=m1 − 92me
=m2 − 58me
=m3 − 44me
=m4

Hence, the Q-value of the fission process is 231.007 MeV.

Ans: 28
(a) Take the D-T nuclear reaction:
It is given that:
Mass of,m1= 2.014102 u
Mass of,m2 = 3.016049 u
Mass ofm3 = 4.002603 u
Mass of,m4 = 1.008665 u
Q-value of the given D-T reaction is:
Q= [m1+ m2m3− m4]c2
= [2.014102 + 3.016049 − 4.002603 −1.008665] c2
= [0.018883 c2] u
But 1 u = 931.5 MeV/c2
Q= 0.018883 × 931.5 = 17.59 MeV
(b) Radius of deuterium and tritium, r2.0 fm = 2 × 10−15m
Distance between the two nuclei at the moment when they touch each other, d = r + r = 4 × 10−15m
Charge on the deuterium nucleus = e
Charge on the tritium nucleus = e
Hence, the repulsive potential energy between the two nuclei is given as:

Where,
0= Permittivity of free space


Hence, 5.76 × 10−14J or of kinetic energy (KE) is needed to overcome the Coulomb repulsion between the two nuclei.
However,it is given that:
KE
Where,
k= Boltzmann constant = 1.38 × 10−23m2 kg s−2K−1
T = Temperature required for triggering the reaction

Hence, the gas must be heated to a temperature of 1.39 × 109K to initiate the reaction.

Ans: 29
It can be observed from the given γ-decay diagram that γ1decays from the 1.088 MeV energy level to the 0 MeV energy level.
Hence, the energy corresponding to γ1-decay is given as:
E1= 1.088 − 0 = 1.088 MeV
hν1= 1.088 × 1.6 × 10−19× 106J
Where,
h= Planck’s constant = 6.6 × 10−34Js
ν1= Frequency of radiation radiated byγ1-decay

It can be observed from the given γ-decay diagram that γ2decays from the 0.412 MeV energy level to the 0 MeV energy level.
Hence, the energy corresponding to γ2-decay is given as:
E2= 0.412 − 0 = 0.412 MeV
hν2= 0.412 × 1.6 × 10−19× 106J
Where,
ν2= Frequency of radiation radiated byγ2-decay

It can be observed from the given γ-decay diagram that γ3decays from the 1.088 MeV energy level to the 0.412 MeV energy level.
Hence, the energy corresponding to γ3-decay is given as:
E3= 1.088 − 0.412 = 0.676 MeV
hν3= 0.676 × 10−19× 106J
Where,
ν3= Frequency of radiation radiated byγ3-decay

Mass of = 197.968233 u
Mass of = 197.966760 u
1 u = 931.5 MeV/c2
Energy of the highest level is given as:

β1decays from the 1.3720995 MeV level to the 1.088 MeV level
Maximum kinetic energy of the β1particle = 1.3720995 − 1.088
= 0.2840995 MeV
β2decays from the 1.3720995 MeV level to the 0.412 MeV level
Maximum kinetic energy of the β2particle = 1.3720995 − 0.412
= 0.9600995 MeV

Ans: 30
(a) Amount of hydrogen, m= 1 kg = 1000 g
1 mole, i.e., 1 g of hydrogen () contains 6.023 × 1023atoms.
1000 g of contains 6.023 × 1023× 1000 atoms.
Within the sun, four nuclei combine and form one nucleus. In this process 26 MeV of energy is released.
Hence,the energy released from the fusion of 1 kgis:

(b) Amount of = 1 kg = 1000 g
1mole, i.e., 235 g of contains 6.023 × 1023atoms.
1000 g ofcontains
It is known that the amount of energy released in the fission of one atom of is 200 MeV.
Hence, energy released from the fission of 1 kg ofis:


Therefore, the energy released in the fusion of 1 kg of hydrogen is nearly 8 times the energy released in the fission of 1 kg of uranium.

Ans: 31
Amount of electric power to be generated, P= 2 × 105MW
10% of this amount has to be obtained from nuclear power plants.
Amount of nuclear power,
= 2 × 104MW
= 2 × 104× 106J/s
= 2 × 1010× 60 × 60 × 24 × 365 J/y
Heat energy released per fission of a 235U nucleus, E= 200 MeV
Efficiency of a reactor = 25%
Hence, the amount of energy converted into the electrical energy per fission is calculated as:

Number of atoms required for fission per year:

1 mole, i.e., 235 g of U235contains 6.023 × 1023atoms.
Mass of 6.023 × 1023atoms of U235 = 235 g = 235 × 10−3kg
Mass of 78840 × 1024atoms of U235

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